Should change the latter of the title to "Who is Second Best". Speaking of second best, I would hand the title to Scarecrow or Bane. One is an inhuman combination of brains and brawn that once broke the Bat, and the other can make the Bat afraid.
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Wonderful suggestion, I do think that the scarecrow is 2nd best but it is tough to pick I am surprised no one has mentioned any female villains like Ivy she can be pretty powerful.