DLCs do not transfer, but they work on the platform you are using your Cross-Saved characters
So, if you Cross-Save by setting your Steam account as main, but keep playing on PS5, and you bought the DLC on PS5, that will work.
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Thank you so much Cris! This 'sounded' like the case, but they stress so hard the 90 day lockout if you deactivate the cross save that I didn't want to be wrong! Cheers legend