Sunsinger isn't good in PvE because of its grenades, which is the main thing people have a problem with. The only good abilities in PvE are self res and flame shield, and even if flame shield gets changed to proc on a kill, there's plenty of trash to slap and kill in PvE so it won't even be that noticeable.
Plus PvE is easy anyways, you shouldn't even need abilities.
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Actually, the grenades are what I like about playing Sunsinger in PvE. Flame Shield is nice, but I get to fulfill the support role with a solar resonance artifact and max discipline.
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Grenades are actually very useful particularly fusions paired with starfire protocol.