Not sure if this is the right category to post this however I found that unless it's intentional support frames no longer trigger ember of benevolence.
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You should probably post this in the Game Issues subcategory of the Help section, cuz I'm pretty sure Support Frames are supposed to be able to trigger Ember of Benevolence.
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To my knowledge it’s only no hesitation because it’s the only one that applies cure which is exclusive to it being the only solar support frame. Adamantite wasn’t able to proc ember of benevolence for me when I initially tested it before too, it’s sad but at least I’m hoping you were testing other support frames that weren’t no hesitation when you did this.