No not really they both make the same
Shooting 2 hallowed knights in Crotas End with GG will create a total of 8-9 orbs
Same thing goes with Sunsingers
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That's true, but only worthwhile if you drop their health to near zero for a gunslinger. I could pop my radiance with any amount of health they may have left and spam gjallarahorns. Gunslinger doesn't have nearly high enough dps to effectively and reliably create orbs.